Integrated manufacturing of REciclable multi-material COmposites for the TRANSport sector
Electrospun polyimide nanofiber?based separators containing carboxyl groups for lithium?ion batteries
The cure characteristic of every NR vulcanizate filled with single filler was a plateau, except for that filled with pyrolytic tire char at 70 phr and all co?filler samples, which showed the reversion because the sulfur amounts in the char together with the added sulfur could shift the curing system.50?phr char?filled sample gave the highest tensile strength, which was about 88% of the 30?phr N330?filled sample.AbstractUntreated pyrolytic tire char was used in natural rubber (STR20) composites as single filler at loadings of 30–70 phr and co?filler with carbon black (N330) at a total loading of 50 phr. The results were compared with rubbers filled with N330 and crumb rubber at 30 phr. The effects of fillers on cure characteristic, crosslink density, filler dispersion in natural rubber vulcanizates and their mechanical properties were investigated. The slight reversions were seen for the cure characteristics of 70 phr?char?filled and all co?filler samples because the sulfur amount in the char together with the added sulfur could shift the vulcanization system from EV to SEV, whereas plateau cure curves were seen for the rest. While the highest tensile strength of char?filled sample was obtained at 50 phr loading, whose tensile strength was about 88% of the N330 sample at 30 phr, 70?phr?char filled sample was superior in surface hardness, abrasion resistance and tear strength to N330 sample at 30 phr. For rubber with co?fillers, the mechanical properties depended on the mass ratio of N330 to pyrolytic tire char. Therefore, it is possible to use untreated char as reinforcing filler for suitable applications according to their properties.
» Publication Date: 23/05/2024
This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement Nº 768737
