Integrated manufacturing of REciclable multi-material COmposites for the TRANSport sector

Supercapacitors have the characteristics of high power density, long cycle life, and fast charge and discharge rates, making them promising alternatives to traditional capacitors and batteries. The use of transition-metal compounds as electrode materials for supercapacitors has been a compelling research topic in recent years because their use can effectively enhance the electrical performance of supercapacitors. The current research on capacitor electrode materials can mainly be divided into the following three categories: carbon-based materials, metal oxides, and conductive polymers. Nickel hydroxide (Ni(OH)2) is a potential electrode material for use in supercapacitors. Depending on the preparation conditions, two crystal phases of nickel hydroxide, α and β, can be produced. When compared to α-NiOH, the structure of β-Ni(OH)2 does not experience ion intercalation. As a result, the carrier transmission rate of α-Ni(OH)2 is slower, and its specific capacitance value is smaller. Its carrier transport rate can be improved by adding conductive materials, such as graphene. β-Ni(OH)2 was chosen as an electrode material for a supercapacitor in this study. Homemade low-pressure chemical vapor deposition graphene (LPCVD-Graphene) conductive material was introduced to modify β-Ni(OH)2 in order to increase its carrier transport rate. The LPCVD method was used to grow high-quality graphene films on three-dimensional (3D) nickel foam substrates. Then, a hydrothermal synthesis method was used to grow β-Ni(OH)2 nanostructures on the 3D graphene/nickel foam substrate. In order to improve the electrical properties of the composite structure, a high-quality graphene layer was incorporated between the nickel hydroxide and the 3D nickel foam substrate. The effect of the conductive graphene layer on the growth of β-Ni(OH)2, as well as its electrical properties and electrochemical performance, was studied. When this β-Ni(OH)2/CVD-Graphene/3D-NF (nickel foam) material was used as the working electrodes of the supercapacitor under a current density of 1 A/g and 3 A/g, they exhibited a specific capacitance of 2015 F/g and 1218.9 F/g, respectively. This capacitance value is 2.62 times higher than that of the structure without modification with a graphene layer. The capacitance value remains at 99.2% even after 1000 consecutive charge and discharge cycles at a current density of 20 A/g. This value also improved compared to the structure without graphene layer modification (94.7%).

» Author: Yang-Ming Lu

» Reference: doi: 10.3390/ma17010023

» Publication Date: 20/12/2023

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