Integrated manufacturing of REciclable multi-material COmposites for the TRANSport sector
Transition?metal?based Catalysts for Electrochemical Synthesis of Ammonia by Nitrogen Reduction Reaction: Advancing the Green Ammonia Economy
Ammonia (NH3), a cornerstone in the chemical industry, has historically been pivotal for producing various valuable products, notably fertilizers. Its significance is further underscored in the modern energy landscape, where NH3 is seen as a promising medium for hydrogen storage and transportation. However, the conventional Haber–Bosch process, which accounts for approximately 170 million ton of NH3 produced globally each year, is energy?intensive and environmentally damaging. The electrochemical nitrogen reduction reaction (NRR) emerges as a sustainable alternative that operates in ambient conditions and uses renewable energy sources. Despite its potential, the NRR faces challenges, including the inherent stability of nitrogen and its competition with the hydrogen evolution reaction. Transition metals, especially ruthenium (Ru) and molybdenum (Mo), have demonstrated promise as catalysts, enhancing the efficiency of the NRR. This review delves into the advancements of Ru and Mo?based catalysts for electrochemical ammonia synthesis, elucidating the NRR mechanisms, and championing the transition towards a greener ammonia economy. It also seeks to elucidate the core principles underpinning the NRR mechanism. This shift aims not only to address challenges inherent to traditional production methods but also to align with the overarching goals of global sustainability.
» Publication Date: 09/10/2023
This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement Nº 768737
