Microwave-assisted synthesis of NiCo-LDH/graphene nanoscrolls composite for supercapacitor
To enhance the electrochemical performance of electrode materials for energy storage devices, utilization the synergistic effect of EDLC-capacitance and pseudocapacitance as well as modification nanostructures are general strategies. Herein, we report the design and synthesis of an array core-shell heterostructure graphene nanoscrolls composite, in which petal-like NiCo-LDH nanoflakes are vertically anchored on the 3D interconnected GNSs skeleton, accomplished by a highly facile microwave-assisted method. This design combines several advantages, including providing more active sites for pseudocapacitive reactions, promoting the collection/transport of electrons and ions, and buffering the volume variation of active matters during cycling. Benefiting from the advantageous nanostructure, the as-obtained [email protected] electrode exhibits a high specific capacitance of 1470 F g?1 at a current density of 1 A g?1 and a long cycle life with 81.6% retention after 1000 cycles.
» Author: Huifang Kuang, Huangqing Zhang, Xiaohong Liu, Yudong Chen, Wengong Zhang, Hong Chen, Qidan Ling
This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement Nº 768737